Kinetic and Thermodynamic Study of Methylene Blue Adsorption on TiO2 and ZnO Thin Films

William Vallejo; Carlos Enrique Diaz-Uribe; Freider Duran

doi:10.3390/ma16124434

Kinetic and Thermodynamic Study of Methylene Blue Adsorption on TiO₂ and ZnO Thin Films

Materials (Basel). 2023 Jun 16;16(12):4434. doi: 10.3390/ma16124434.

Authors

William Vallejo¹, Carlos Enrique Diaz-Uribe¹, Freider Duran¹

Affiliation

¹ Grupo de Fotoquímica y Fotobiología, Universidad del Atlántico, Puerto Colombia 81007, Colombia.

Abstract

In this work, we fabricated and characterized ZnO and TiO₂ thin films, determining their structural, optical, and morphological properties. Furthermore, we studied the thermodynamics and kinetics of methylene blue (MB) adsorption onto both semiconductors. Characterization techniques were used to verify thin film deposition. The semiconductor oxides reached different removal values, 6.5 mg/g (ZnO) and 10.5 mg/g (TiO₂), after 50 min of contact. The pseudo-second-order model was suitable for fitting the adsorption data. ZnO had a greater rate constant (45.4 × 10^-3) than that of TiO₂ (16.8 × 10^-3). The removal of MB by adsorption onto both semiconductors was an endothermic and spontaneous process. Finally, the stability of the thin films showed that both semiconductors maintained their adsorption capacity after five consecutive removal tests.

Keywords: TiO2; ZnO; adsorption; environmental remediation; thermodynamics; thin films.

Grants and funding

This research was funded by Universidad del Atlántico, research project CB398-Cll2022.