A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium

Chem Commun (Camb). 2023 Jul 13;59(57):8826-8829. doi: 10.1039/d3cc02447d.

Abstract

We report an iridium system constructed around a long-tethered PGeP ligand that facilitates access to the less common germylene form, so far unreported for an 'NHC-type' Ge ligand. Its bonding is substantiated by computational studies and we have demonstrated its use for the catalytic dehydrogenation of formic acid, highlighting the potential of this underdeveloped type of ligand.

MeSH terms

  • Formates*
  • Iridium*
  • Ligands

Substances

  • germylene
  • Iridium
  • formic acid
  • Ligands
  • Formates