Rare-earth manganese pyrochlores (R2Mn2O7) are frustrated magnetic materials, which previously have only been accessed using expensive high-pressure and high-temperature synthesis. In the present work, we demonstrate a convenient synthetic approach to synthesize R2Mn2O7 pyrochlores at ambient pressure. A series of pyrochlores (R = Y, Ho-Lu) were prepared by a simple and cost-effective molten salt method using NaCl and KCl as the flux. Moreover, phase-selectivity was demonstrated for yttrium manganese oxides (YMnO3 and Y2Mn2O7) by a simple variation of synthesis temperature and precursors-to-chlorides ratio. The synthetic procedure does not require high pressures or temperatures nor oxygen flow. All synthesized pyrochlores demonstrated ferromagnetic behavior at low temperature, and the magnetic properties were in good agreement with those of high-pressure-synthesized materials. The versatility of the method was confirmed by the preparation of a mixed-rare earth Y0.4Er0.4Tm0.4Yb0.4Lu0.4Mn2O7 solid solution─a compositionally complex high-entropy oxide.