Creation of AIEgens with high brightness is compactly related to acquiring optimum AIE capabilities and still faces challenges. This study proposes an ingenious structurally regulative approach for preparing ultrabright AIEgens, taking iridium complexes as the model. The incremental rotational activity of substituents obtained by fine adjustment of the stereoscopic configuration efficaciously activates the AIE of iridium complexes and synchronously imparts high-brightness luminescence. Subsequently, benefitting from the ultrabright AIE, high-resolution visualization of latent fingerprints (LFPs) is achieved on diverse substrates by transient immersion in a solution of the AIE-active iridium complex (Ir3) for 60 s. The LFPs stained by Ir3 are integral and distinct enough to possess level 1-3 detail features, which allow precisely realizing personal identification. The LFP photograph emerges inconspicuous attenuation of contrast when aged under ambient light for 10 days and then being continuously irradiated with high-power ultraviolet light for 1 h, reflecting extraordinary aging resistance. Notably, the ultrabright AIE of Ir3 with room-temperature phosphorescence feature successfully achieves enhanced visualization of local fingerprint details with ultrahigh contrast. This LFP visualization protocol based on the ultrabright AIEgens is practical and provides a reliable solution for forensic investigations in actual scenarios.
Keywords: Aggregation-induced emission; Aging resistance; Imaging definition; Iridium; Latent fingerprint.
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