Cycling of phosphorus from wastewater to fertilizer using wood ash after energy production

Abstract

Quercus wood was used for thermal energy production, and wood bottom ash (WDBA) was used as a medium for water purification and soil fertilizer in accordance with the recently proposed food-water-energy nexus concept. The wood contained a gross calorific value of 14.83 MJ kg^-1, and the gas generated during thermal energy production has the advantage of not requiring a desulfurization unit due to its low sulfur content. Wood-fired boilers emit less CO₂ and SO_X than coal boilers. The WDBA had a Ca content of 66.0%, and Ca existed in the forms of CaCO₃ and Ca(OH)₂. WDBA absorbed P by reacting with Ca in the form of Ca₅(PO₄)₃OH. Kinetic and isotherm models revealed that the results of the experimental work were in good agreement with the pseudo-second-order and Langmuir models, respectively. The maximum P adsorption capacity of WDBA was 76.8 mg g^-1, and 6.67 g L^-1 of WDBA dose could completely remove P in water. The toxic units of WDBA tested using Daphnia magna were 6.1, and P adsorbed WDBA (P-WDBA) showed no toxicity. P-WDBA was used as an alternative P fertilizer for rice growth. P-WDBA application resulted in significantly greater rice growth in terms of all agronomic values compared to N and K treatments without P. This study proposed the utilization of WDBA, obtained from thermal energy production, to remove P from wastewater and replenish P in the soil for rice growth.

Keywords: Hydroxyapatite; Phosphorus fertilizer; Phosphorus removal; Rice growth; Thermal energy production; Wood ash.