In this work, a facile synthesis method was adopted to synthesize MOF-14 with mesoporous structure. The physical properties of the samples were characterized by PXRD, FESEM, TEM and FT-IR spectrometry. By coating the mesoporous-structure MOF-14 on the surface of a quartz crystal microbalance (QCM), the fabricated gravimetric sensor exhibits high sensitivity to p-toluene vapor even at trace levels. Additionally, the limit of detection (LOD) of the sensor obtained experimentally is lower than 100 ppb, and the theoretical detection limit is 57 ppb. Furthermore, good gas selectivity and fast response (15 s) and recovery (20 s) abilities are also illustrated along with high sensitivity. These sensing data indicate the excellent performance of the fabricated mesoporous-structure MOF-14-based p-xylene QCM sensor. On the basis of temperature-varying experiments, an adsorption enthalpy of -59.88 kJ/mol was obtained, implying the existence of moderate and reversible chemisorption between MOF-14 and p-xylene molecules. This is the crucial factor that endows MOF-14 with exceptional p-xylene-sensing abilities. This work has proved that MOF materials such as MOF-14 are promising in gravimetric-type gas-sensing applications and worthy of future study.
Keywords: VOC detection; adsorption enthalpy; metal−organic frameworks (MOFs); quartz crystal microbalance.