Enhancing Cu2+ Ion Removal: An Innovative Approach Utilizing Modified Frankincense Gum Combined with Multiwalled Carbon Tubes and Iron Oxide Nanoparticles as Adsorbent

Molecules. 2023 Jun 1;28(11):4494. doi: 10.3390/molecules28114494.

Abstract

Aquatic pollution, which includes organic debris and heavy metals, is a severe issue for living things. Copper pollution is hazardous to people, and there is a need to develop effective methods for eliminating it from the environment. To address this issue, a novel adsorbent composed of frankincense-modified multi-walled carbon nanotubes (Fr-MMWCNTs) and Fe3O4 [Fr-MWCNT-Fe3O4] was created and subjected to characterization. Batch adsorption tests showed that Fr-MWCNT-Fe3O4 had a maximum adsorption capacity of 250 mg/g at 308 K and could efficiently remove Cu2+ ions over a pH range of 6 to 8. The adsorption process followed the pseudo-second-order and Langmuir models, and its thermodynamics were identified as endothermic. Functional groups on the surface of modified MWCNTs improved their adsorption capacity, and a rise in temperature increased the adsorption efficiency. These results highlight the Fr-MWCNT-Fe3O4 composites' potential as an efficient adsorbent for removing Cu2+ ions from untreated natural water sources.

Keywords: Cu adsorption; adsorption isotherm; adsorption kinetics; frankincense; multiwalled carbon.

MeSH terms

  • Adsorption
  • Copper / chemistry
  • Frankincense*
  • Humans
  • Hydrogen-Ion Concentration
  • Kinetics
  • Magnetic Iron Oxide Nanoparticles
  • Nanotubes, Carbon* / chemistry
  • Water Pollutants, Chemical* / chemistry
  • Water Purification* / methods

Substances

  • Copper
  • Frankincense
  • Nanotubes, Carbon
  • Water Pollutants, Chemical