5-[(4-Methyl-phen-yl)sulfon-yl]-1-phenyl-thio-pyrano[4,3- b]indole-3(5 H)-thione di-chloro-methane monosolvate

Benjamin Dassonneville; Dieter Schollmeyer; Heiner Detert

doi:10.1107/S2414314623003541

5-[(4-Methyl-phen-yl)sulfon-yl]-1-phenyl-thio-pyrano[4,3- b]indole-3(5 H)-thione di-chloro-methane monosolvate

IUCrdata. 2023 May 12;8(Pt 5):x230354. doi: 10.1107/S2414314623003541. eCollection 2023 May.

Authors

Benjamin Dassonneville¹, Dieter Schollmeyer¹, Heiner Detert¹

Affiliation

¹ University of Mainz, Department of Chemistry, Duesbergweg 10-14, 55099 Mainz, Germany.

Abstract

Rhodium-catalyzed [2+2+2] cyclo-addition of carbon di-sulfide to o,N-dialkynyl-tosyl-anilines gives two isomeric indolo-thio-pyran-thio-nes, a violet and a red isomer. This is the first crystal structure of a red isomer, which crystallizes with one solvent mol-ecule of di-chloro-methane in the asymmetric unit, C₂₄H₁₇NO₂S₃·CH₂Cl₂. In the extended structure, centrosymmetric pairs of the planar annulated system are arranged in strands and solvent mol-ecules fill the space between the strands.

Keywords: annulated heterocycles; crystal structure; sulfur.