Diethofencarb (DFC) is widely used in agriculture to fight against plant fungal attacks and enhance food crop production. On the other hand, the National food safety standard has set the overall maximum residual limit of DFC to be 1 mg/kg. Hence it becomes essential to limit their usage, and it is vital to quantify the amount of DFC present in real-life samples to safeguard the health and environmental well-being. Here, we introduce a simple hydrothermal procedure for preparing vanadium carbide (VC) anchored by ZnCr-LDH. The sustainably designed electrochemical sensor for the detection of DFC portrayed high electro-active surface area, conductivity, rapid-electron transport ratio, and high ion diffusion parameters. The obtained structural and morphological information confirms the enriched electrochemical activity of the ZnCr-LDH/VC/SPCE towards DFC. The ZnCr-LDH/VC/SPCE electrode has displayed exceptional characteristics with DPV resulting in a vast linear response (0.01-228 μM), and lower LOD (2 nM) with high sensitivity. Real-sample analysis was carried out to demonstrate the specificity of the electrode with an acceptable recovery in both water (±98.75-99.70%) and tomato (±98.00-99.75%) samples.
Keywords: 2D-2D nanomaterials; Carbides; Environmental monitoring.; Fungicide; ZnCr–LDH.
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