Two novel fluorescent probes based on quinolinone for continuous recognition of Al3+ and ClO

Abstract

On the basis of classical Schiff base reaction, two novel and efficient fluorescent probes (DQNS, DQNS1) were designed and synthesized by introducing Schiff base structure into dis-quinolinone unit for structural modification, which can be used to detect Al³⁺ and ClO^-. Because the power supply capacity of H is weaker than that of methoxy, DQNS shows better optical performance: a large Stokes Shift (132 nm), identify Al³⁺ and ClO^- with high sensitivity and selectivity, low detection limit (29.8 nM and 25 nM) and fast response time (10 min and 10 s). Through the working curve and NMR titration experiment, the recognition mechanism of Al³⁺ and ClO^- (PET and ICT) probes are confirmed. Meanwhile, it is speculated that the probe has continuity for the detection of Al³⁺ and ClO^-. Furthermore, DQNS detection of Al³⁺ and ClO^- was applied to real water samples and living cell imaging.

Keywords: Al(3+); ClO(−); Continuity recognition; Fluorescent probe; Quinolinone.