The present study aims in the developing of new soft transducers based on sophisticated stimuli-responsive microgels that exhibit spontaneous self-assembly forming cohesive films with conductive and mechanoelectrical properties. For that, oligo(ethylene glycol)-based stimuli-responsive microgels have been synthesized using bio-inspired catechol cross-linkers by one-step batch precipitation polymerization in aqueous media. Then, 3,4-ethylene dioxyyhiophene (EDOT) has been directly polymerized onto stimuli-responsive microgels using catechol groups as the unique dopant. PEDOT location is dependent on the cross-linking density of microgel particles and EDOT amount used. Moreover, the spontaneous cohesive film formation ability of the waterborne dispersion after evaporation at soft application temperature is demonstrated. The films obtained present conductivity and enhanced mechanoelectrical properties triggered by simple finger compression. Both properties are function of the cross-linking density of the microgel seed particles and PEDOT amount incorporated. In addition, to obtain maximum electrical potential generated and the possibility to amplify it, several films in series were demonstrated to be efficient. The present material can be a potential candidate for biomedical, cosmetic, and bioelectronic applications.
Keywords: bio-inspired; catechol; conductivity; mechano-electricity; microgels; self-assembly; stimuli-responsiveness.