Multivariate optimization of characteristic parameters of continuous-flow system with a front buffer tank for industrial reverse osmosis concentrate treatment

Abstract

Industrial reverse osmosis concentrate (ROC) was electrochemically oxidized using a continuous-flow system (CFS) with a front buffer tank. Multivariate optimization including Plackett-Burman (PBD) and central composite design based on response surface method (CCD-RSM) was implemented to investigate the effects of characteristic (e.g., recirculation ratio (R value), ratio of buffer tank and electrolytic zone (R_V value)) and routine (e.g., current density (i), inflow linear velocity (v) and electrode spacing (d)) parameters. R, v values and current density significantly influenced chemical oxygen demand (COD) and NH₄⁺-N removal and effluent active chlorine species (ACS) level, while electrode spacing and R_V value had negligible effects. High chloride content of industrial ROC facilitated the generation of ACS and subsequent mass transfer, low hydraulic retention time (HRT) of electrolytic cell improved the mass transfer efficiency, and high HRT of buffer tank prolonged the reaction between the pollutants and oxidants. The significance levels of COD removal, energy efficiency, effluent ACS level and toxic byproduct level CCD-RSM models were validated by statistical test results, including higher F value than critical effect value, lower P value than 0.05, low deviation between predicted and observed values, and normal distribution of calculated residuals. The highest pollutant removal was achieved at a high R value, a high current density and a low v value; the highest energy efficiency was achieved at a high R, a low current density and a high v value; the lowest effluent ACS and toxic byproduct levels were achieved at a low R value, a low current density and a high v value. Following the multivariate optimization, the optimum parameters were decided to be v = 1.2 cm h^-1, i ≥ 8 mA cm^-2, d ≥ 4, R_V = 10-20 and R = 1 to achieve better effluent quality (i.e., lower effluent pollutant, ACS and toxic byproduct levels).

Keywords: Electrochemical treatment; High effluent quality; Industrial reverse osmosis concentrate; Multivariate optimization; Toxic byproduct control.