Flexible Synergistic MoS2 Quantum Dots/PEDOT: PSS Film Sensor for Acetaldehyde Sensing at Room Temperature

Ling Jin; Kai Yang; Lifan Chen; Ruran Yan; Lifang He; Mingfu Ye; Hongbin Qiao; Xiangfeng Chu; Hong Gao; Kui Zhang

doi:10.1021/acs.analchem.3c00365

Flexible Synergistic MoS₂ Quantum Dots/PEDOT: PSS Film Sensor for Acetaldehyde Sensing at Room Temperature

Anal Chem. 2023 Jun 13;95(23):8859-8868. doi: 10.1021/acs.analchem.3c00365. Epub 2023 May 30.

Authors

Ling Jin¹, Kai Yang¹, Lifan Chen¹, Ruran Yan¹, Lifang He¹, Mingfu Ye^{1

2}, Hongbin Qiao¹, Xiangfeng Chu¹, Hong Gao¹, Kui Zhang¹

Affiliations

¹ School of Chemistry and Chemical Engineering, Anhui University of Technology, Ma'anshan, Anhui 243032, China.
² Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China.

PMID: 37253053
DOI: 10.1021/acs.analchem.3c00365

Abstract

Acetaldehyde (CH₃CHO) is known as a primary carcinogen, and the development of wearable gas sensors for its detection at room temperature has rarely been rarely reported. Herein, MoS₂ quantum dots (MoS₂ QDs) have been employed to dope with poly(3,4-ethylenedioxythiophene): polystyrenesulfonate (PEDOT: PSS) via a simple in situ polymerization technique, and the CH₃CHO gas-sensing properties of the resultant flexible and transparent film were investigated. MoS₂ QDs had been evenly dispersed into the polymer, and it was shown that PEDOT: PSS doped with the 20 wt % MoS₂ QDs sensor exhibited the highest response value of 78.8% against 100 ppm CH₃CHO and its detection limit reached 1 ppm. Moreover, the sensor response remained stable for more than 3 months. In particular, the different bending angles (from 60 to 240°) had little effect on the sensor response to CH₃CHO. The possible reason for the enhanced sensing properties was attributed to the large number of reaction sites on the MoS₂ QDs and the direct charge transfer between the MoS₂ QDs and PEDOT: PSS. This work suggested a platform to inspire MoS₂ QDs-doping PEDOT: PSS materials as wearable gas sensors for highly sensitive chemoresistive sensors to detect CH₃CHO at room temperature.