Carbon dioxide (CO2) is a major greenhouse gas responsible for the increase in global temperature, making carbon capture and sequestration (CCS) crucial for controlling global warming. Traditional CCS methods such as absorption, adsorption, and cryogenic distillation are energy-intensive and expensive. In recent years, researchers have focused on CCS using membranes, specifically solution-diffusion, glassy, and polymeric membranes, due to their favorable properties for CCS applications. However, existing polymeric membranes have limitations in terms of permeability and selectivity trade-off, despite efforts to modify their structure. Mixed matrix membranes (MMMs) offer advantages in terms of energy usage, cost, and operation for CCS, as they can overcome the limitations of polymeric membranes by incorporating inorganic fillers, such as graphene oxide, zeolite, silica, carbon nanotubes, and metal-organic frameworks. MMMs have shown superior gas separation performance compared to polymeric membranes. However, challenges with MMMs include interfacial defects between the polymeric and inorganic phases, as well as agglomeration with increasing filler content, which can decrease selectivity. Additionally, there is a need for renewable and naturally occurring polymeric materials for the industrial-scale production of MMMs for CCS applications, which poses fabrication and reproducibility challenges. Therefore, this research focuses on different methodologies for carbon capture and sequestration techniques, discusses their merits and demerits, and elaborates on the most efficient method. Factors to consider in developing MMMs for gas separation, such as matrix and filler properties, and their synergistic effect are also explained in this Review.
© 2023 The Authors. Published by American Chemical Society.