Colloidal photonic crystals, which are three-dimensional periodic structures of monodisperse submicron-sized particles, are expected to be suitable for novel photonic applications and color materials. In particular, nonclose-packed colloidal photonic crystals immobilized in elastomers exhibit significant potential for use in tunable photonic applications and strain sensors that detect strain based on color change. This paper reports a practical method for preparing elastomer-immobilized nonclose-packed colloidal photonic crystal films with various uniform Bragg reflection colors using one kind of gel-immobilized nonclose-packed colloidal photonic crystal film. The degree of swelling was controlled by the mixing ratio of the precursor solutions, which used a mixture of solutions with high and low affinities for the gel film as the swelling solvent. This facilitated color tuning over a wide range, enabling the facile preparation of elastomer-immobilized nonclose-packed colloidal photonic crystal films with various uniform colors via subsequent photopolymerization. The present preparation method can contribute to the development of practical applications of elastomer-immobilized tunable colloidal photonic crystals and sensors.
Keywords: colloidal crystals; color materials; elastomers; stimuli-sensitive materials; tunable photonic crystals.