Engineering multilayer catalytic interfaces with N, S co-regulation for high performance water splitting

Abstract

The rational design of hierarchical nano-heterojunction electrocatalysts with efficient and durable water splitting performance is a hot research topic in the field of sustainable energy conversion. Herein, chemical vapor deposition methods are exploited to dope N and S elements in a core-shell structured Co₃O₄@NiMoO₄ with a layered structure (N, S-Co₃O₄@NiMoO₄/NF₄₀₀). The close contact between Co₃O₄ nanowires and N, S co-doped NiMoO₄ cubic arrays facilitates electron transfer. The electronic structure of Ni, Co and Mo atoms could be optimized to enhance their electrical conductivity by modulation of N and S atoms. At current densities of 10 and 200 mA cm^-2, N, S-Co₃O₄@NiMoO₄/NF₄₀₀ has an overpotential of 200, 300 and 71 160 mV for the oxygen evolution reaction and hydrogen evolution reaction, respectively. Its water splitting voltages are 1.45 V and 2 V at 10 and 200 mA cm^-2. In addition, N, S-Co₃O₄@NiMoO₄/NF₄₀₀ can operate stably for 100 h at a current density of 50 mA cm^-2. This work provides a new approach to designing bifunctional catalysts with hierarchical heterogeneous structures co-regulated by dual elements.

Keywords: Hydrogen evolution reaction; N,S co-regulation; Overall water splitting; Oxygen evolution reaction.