Preliminary study of geochemical speciation of copper and nickel in coastal sediments in Surabaya, Indonesia

Abstract

Surabaya is one of the big coastal cities in Indonesia with rapid municipal development. Thus, the investigation on the metal's geochemical speciation in the coastal sediment is required to assess the environmental quality by studying their mobility, bioavailability, and toxicity. This study is aimed at evaluating the condition of the Surabaya coast by assessing copper and nickel fractionations and total concentrations of both metals in sediments. Environmental assessments were performed by using geo-accumulation index (Igeo), contamination factor (CF), and pollution load index (PLI) for existing total heavy metal data and by using individual contamination factor (ICF) and risk assessment code (RAC) for metal fractionations. Copper speciation was observed geochemically in the fraction order of residual (9.21 - 40.08 mg/kg) > reducible (2.33 - 11.98 mg/kg) > oxidizable (0.75 - 22.71 mg/kg) > exchangeable (0.40 - 2.06 mg/kg), while the detected fraction order of nickel was residual (5.16 - 13.88 mg/kg) > exchangeable (2.33 - 5.95 mg/kg) > reducible (1.42 - 4.74 mg/kg) > oxidizable (1.62 - 3.88 mg/kg). Different fraction levels were found for nickel speciation wherein its exchangeable fraction was higher than copper, even though the residual fraction was dominant for both copper and nickel. The total metal concentrations of copper and nickel were found in the range of 13.5 - 66.1 mg/kg dry weight and 12.7 - 24.7 mg/kg dry weight, respectively. Despite the fact that almost all index values are detected low through total metal assessment, the port area is indicated to be in the moderate contamination category for copper. Through the assessment of metal fractionation, copper is classified into the low contamination and low-risk category, while nickel is categorized into the moderate contamination level and medium risk to the aquatic environment. Although the coast of Surabaya generally remains in the safe category for living habitat, certain sites had relatively high metal concentrations estimated to have originated from anthropogenic activities.

Keywords: Coastal sediments; Copper; Geochemical speciation; Metal fractionation; Nickel; Total metal.