Statically and dynamically flexible hydrogen-bonded frameworks based on 4,5,9,10-tetrakis(4-carboxyphenyl)pyrene

Taito Hashimoto; Ryusei Oketani; Asato Inoue; Kohei Okubo; Kouki Oka; Norimitsu Tohnai; Kazuhide Kamiya; Shuji Nakanishi; Ichiro Hisaki

doi:10.1039/d3cc01877f

Statically and dynamically flexible hydrogen-bonded frameworks based on 4,5,9,10-tetrakis(4-carboxyphenyl)pyrene

Chem Commun (Camb). 2023 Jun 8;59(47):7224-7227. doi: 10.1039/d3cc01877f.

Authors

Taito Hashimoto¹, Ryusei Oketani^{1

2}, Asato Inoue¹, Kohei Okubo³, Kouki Oka^{3

4}, Norimitsu Tohnai³, Kazuhide Kamiya^{1

2}, Shuji Nakanishi^{1

2}, Ichiro Hisaki^{1

2}

Affiliations

¹ Division of Chemistry, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan. i.hisaki.es@osaka-u.ac.jp.
² Research Center for Solar Energy Chemistry, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan.
³ Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
⁴ Center for Future Innovation (CFi), Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.

PMID: 37221861
DOI: 10.1039/d3cc01877f

Abstract

Aperture shape and size of flexible hydrogen-bonded organic frameworks (HOF) were statically modulated using various aromatic solvents, and dynamically changed by desorption and adsorption of the solvent molecules.

MeSH terms

Adsorption
Hydrogen*
Pyrenes*
Solvents

Substances

pyrene
Pyrenes
Hydrogen
Solvents