Open-[60]fullerene-aniline conjugates with near-infrared absorption

RSC Adv. 2023 May 12;13(21):14575-14579. doi: 10.1039/d3ra02113k. eCollection 2023 May 9.

Abstract

Two open-[60]fullerene-aniline conjugates were synthesized, in which the two-fold addition of diamine gave a thiazolidine-2-thione ring on the [60]fullerene cage in the presence of CS2. By increasing the number of N,N-dimethylaniline moieties, the absorption edge was considerably shifted up to 1200 nm owing to effective acceptor-donor interactions.