Polymer electrolytes (PEs) are a promising alternative to overcome shortcomings of conventional lithium ion batteries (LiBs) and make them safer for users. Introduction of self-healing features in PEs additionally leads to prolonged life-time of LIBs, thus tackling cost and environmental issues. We here present solvent free, self-healable, reprocessable, thermally stable, conductive poly(ionic liquid) (PIL) consisting of pyrrolidinium-based repeating units. PEO-functionalized styrene was used as a co-monomer for improving mechanical properties and introducing pendant OH groups in the polymer backbone to act as a transient crosslinking site for boric acid, leading to the formation of dynamic boronic ester bonds, thus forming a vitrimeric material. Dynamic boronic ester linkages allow reprocessing (at 40 °C), reshaping and self-healing ability of PEs. A series of vitrimeric PILs by varying both monomers ratio and lithium salt (LiTFSI) content was synthesized and characterized. The conductivity reached 10-5 S cm-1 at 50 °C in the optimized composition. Moreover, the PILs rheological properties fit the required melt flow behavior (above 120 °C) for 3D printing via fused deposition modeling (FDM), offering the possibility to design batteries with more complex and diverse architectures.
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