Surface engineering of conventional catalysts using polymeric coating has been extensively explored for producing hybrid catalytic material with enhanced activity, high mechanical and thermal stability, enhanced productivity, and selectivity of the desired product. The present review discusses in detail the state-of-the-art knowledge on surface modification of catalysts, namely photocatalysts, electrocatalysts, catalysts for photoelectrochemical reactions, and catalysts for other types of reactions, such as hydrodesulfurization, carbon dioxide cycloaddition, and noble metal-catalyzed oxidation/reduction reactions. The various techniques employed for the polymer coating of catalysts are discussed and the role of polymers in enhancing the catalytic activity is critically analyzed. The review further discusses the applications of biodegradable and biocompatible natural polysaccharide-based polymers, namely, chitosan and polydopamine as prospective coating material.
Keywords: biopolymer; catalytic activity; functional coatings; polymeric coating; productivity.