Master equation simulations of the unimolecular reaction dynamics of the Criegee intermediate methacrolein oxide (MACR oxide) have been performed under a variety of temperature and pressure conditions. These simulations provide insight into how the unimolecular kinetics vary across temperatures spanning the range 288-320 K. This work has incorporated a new potential energy surface and includes the anti-to-syn and cis-to-trans conformational dynamics of MACR oxide, as well as the unimolecular reactions to form dioxirane and dioxole species. The competition between the unimolecular reactivity of MACR oxide and previously documented bimolecular reactivity of MACR oxide with water vapor is explored, focusing on how this competition is affected by changes in atmospheric conditions. The impact on the role of MACR oxide as an atmospheric oxidant of SO2 is noted.