{μ-2,2'-(Ethane-1,2-di-yl)bis-[4,6-bis-(tri-methyl-sil-yl)-1,3-di-hydro-cyclo-penta-[ c]pyrrol-5-one]}bis-[tri-carbonyl-iron(0)]

IUCrdata. 2023 Apr 21;8(Pt 4):x230346. doi: 10.1107/S2414314623003462. eCollection 2023 Apr.

Abstract

The binuclear title compound, [Fe2(C28H48N2O2Si4)(CO)6], consists of two central iron(0) atoms, each of them surrounded by a cyclo-penta-dienone moiety and three carbonyl ligands in a three-legged piano-stool shape. Furthermore, the bis-(cyclo-penta-dienone) ligand acts as a bridge between the two metal atoms.

Keywords: binuclear complex; crystal structure; cyclo­penta­dienone ligand; iron carbonyl complex.

Grants and funding

Funding for this research was provided by: Leibniz Campus ‘ComBioCat’ (award No. W10/2018).