Li metal anode has been recognized as the most promising anode for its high theoretical capacity and low reduction potential. But its large-scale commercialization is hampered because of the infinite volume expansion, severe side reactions, and uncontrollable dendrite formation. Herein, the self-supporting porous lithium foam anode is obtained by a melt foaming method. The adjustable interpenetrating pore structure and dense Li3 N protective layer coating on the inner surface enable the lithium foam anode with great tolerance to electrode volume variation, parasitic reaction, and dendritic growth during cycling. Full cell using high areal capacity (4.0 mAh cm-2 ) LiNi0.8Co0.1Mn0.1 (NCM811) cathode with the N/P ratio of 2 and E/C ratio of 3 g Ah-1 can stably operate for 200 times with 80% capacity retention. The corresponding pouch cell has <3% pressure fluctuation per cycle and almost zero pressure accumulation.
Keywords: foaming agent; lithium foam; lithium metal batteries; solid electrolyte interphase (SEI); zero pressure expansion.
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