In this work, cotton stalks (Gossypium barbadense) and date palm stones (Phoenix dactylifera) have been used as biosorbents to remove cadmium; Cd(II), lead; Pb(II), and zinc; Zn(II) from mono- and multi-solutions. Each biosorbent was characterized using SEM-EDX, and FT-IR. The findings showed that pH, dose, contact time, metal concentration, and particle size affect the treatment process. The adsorption pattern was Pb(II) > Cd(II) > Zn(II) for both biosorbents. The adsorption performance of cotton stalks was higher than that of date palm stones. The fitted maximum uptake capacities; qm of cotton stalks were higher than those of date palm stones. The maximum adsorption at optimum conditions of Pb(II), Cd(II), and Zn(II) with cotton stalks were 98%, 92.1%, and 78.9%, respectively, within 30 min. While the maximum adsorption of Pb(II), Cd(II), and Zn(II) with date palm stones were 94.6%, 76%, and 68.6%, respectively. Results confirmed the antagonistic effect of heavy metal removal at optimum conditions. Biosorbents could remove ~ 100% of the metal ions from real wastewater samples. Regeneration investigation revealed a successful reusability of both biosorbents for four cycles.
Keywords: Cadmium/lead/zinc; Desorption; Models; Multi-metal adsorption; Real wastewater.
© 2023. The Author(s).