Oxygen vacancies-rich Cu-W18O49 nanorods supported on reduced graphene oxide for electrochemical reduction ofN2to NH3

Abstract

High-performance nitrogen fixation is severely limited by the efficiency and selectivity of a catalyst of electrochemical nitrogen reduction reaction (NRR) under ambient conditions. Here, the RGO/WOCu (reduced graphene oxide and Cu-doping W₁₈O₄₉) composite catalysts with abundant oxygen vacancies are prepared by the hydrothermal method. The obtained RGO/WOCu achieves an enhanced NRR performance (NH₃ yield rate:11.4 μg h^-1 mg_cat^-1, Faradaic efficiency: 4.4%) at -0.6 V (vs. RHE) in 0.1 mol L^-1 Na₂SO₄ solution. Furthermore, the NRR performance of the RGO/WOCu still keeps at 95% after four cycles, demonstrating its excellent stability. The Cu⁺-doping increases the concentration of oxygen vacancies, which is conducive to the adsorption and activation of N₂. Meanwhile, the introduction of RGO further improves the electrical conductivity and reaction kinetics of the RGO/WOCu due to the high specific surface area and conductivity. This work provides a simple and effective method for efficient electrochemical reduction ofN₂.

Keywords: Cu(+)-doping; NRR; Oxygen vacancies; Reduced graphene oxide; W(18)O(49).