Graphene-based strontium niobate-zinc oxide heterojunction photocatalyst for effective reduction of hexavalent chromium

Abstract

A hydrothermal technique was employed to synthesize a Sr₂Nb₂O₇-rGO-ZnO (SNRZ) ternary nanocatalyst, in which ZnO and Sr₂Nb₂O₇ were deposited on reduced graphene oxide (rGO) sheets. The surface morphologies, optical properties, and chemical states, of the photocatalysts were characterized to understand their properties. The SNRZ ternary photocatalyst was superior over the reduction of Cr (VI) to harmless Cr (III) compared to the efficiencies obtained using bare, binary, and composite catalysts. The effects of various parameters, including the solution pH and weight ratio, on the photocatalytic reduction of Cr (VI) were investigated. The highest photocatalytic reduction performance (97.6%) was achieved at pH 4 and a reaction time of 70 min. Photoluminescence emission measurements were used to confirm efficient charge migration and separation across the SNRZ, which improved the reduction of Cr (VI). A feasible reduction mechanism for the SNRZ photocatalyst is proposed. This study presents an effective, inexpensive, non-toxic, and stable catalyst, for the reduction of Cr (VI) to Cr (III) using SNRZ ternary nanocatalysts.

Keywords: Chromium (VI) reduction; Hydrothermal technique; Photocatalytic reduction; Strontium niobate-zinc oxide.