Optimization of bandgap reduction in 2-dimensional GO nanosheets and nanocomposites of GO/iron-oxide for electronic device applications

Abstract

In this report we have developed different fabrication parameters to tailor the optical bandgap of graphene oxide (GO) nanosheets to make it operational candidate in electronic industry. Here we performed two ways to reduce the bandgap of GO nanosheets. First, we have optimized the oxidation level of GO by reducing amount of oxidizing agent (i.e. KMnO₄) to control the sp²/sp³ hybridization ratio for a series of GO nanosheets samples. We noticed the reduction in primary band edge 3.93-3.2 eV while secondary band edge 2.98-2.2 eV of GO nanosheets as the amount of KMnO₄ is decreased from 100 to 30%. Second, we have fabricated a series of 2-dimensional nanocomposites sample containing GO/Iron-oxide by using a novel synthesis process wet impregnation method. XRD analysis of synthesized nanocomposites confirmed the presence of both phases,[Formula: see text]-Fe₂O₃ and Fe₃O₄ of iron-oxide with prominent plane (001) of GO. Morphological investigation rules out all the possibilities of agglomerations of iron oxide nanoparticles and coagulation of GO nanosheets. Elemental mapping endorsed the homogeneous distribution of iron oxide nanoparticles throughout the GO nanosheets. Raman spectroscopy confirmed the fairly constant I_D/I_G ratio and FWHM of D and G peaks, thus proving the fact that the synthesis process of nanocomposites has no effect on the degree of oxidation of GO flakes. Red shift in G peak position of all the nanocomposites samples showed the electronic interaction among the constituents of the nanocomposite. Linear decrease in the intensity of PL (Photoluminescence) spectra with the increasing of Iron oxide nanoparticles points towards the increased interaction among the iron oxide nanoparticles and GO flakes. Optical absorption spectroscopy reveals the linear decrease in primary edge of bandgap from 2.8 to 0.99 eV while secondary edge decrease 3.93-2.2 eV as the loading of [Formula: see text]-Fe₂O₃ nanoparticles is increased from 0 to 5% in GO nanosheets. Among these nanocomposites samples 5%-iron-oxide/95%-GO nanosheet sample may be a good contestant for electronic devices.