Rapid Detection of Cd2+ Ions in the Aqueous Medium Using a Highly Sensitive and Selective Turn-On Fluorescent Chemosensor

Abstract

Herein, a novel optical chemosensor, (CM1 = 2, 6-di((E)-benzylidene)-4-methylcyclohexan-1-one), was designed/synthesized and characterized by ¹H-NMR and FT-IR spectroscopy. The experimental observations indicated that CM1 is an efficient and selective chemosensor towards Cd²⁺, even in the presence of other metal ions, such as Mn²⁺, Cu²⁺, Co^2+, Ce³⁺, K⁺, Hg²⁺,^, and Zn²⁺ in the aqueous medium. The newly synthesized chemosensor, CM1, showed a significant change in the fluorescence emission spectrum upon coordination with Cd²⁺. The formation of the Cd²⁺ complex with CM1 was confirmed from the fluorometric response. The 1:2 combination of Cd²⁺ with CM1 was found optimum for the desired optical properties, which was confirmed through fluorescent titration, Job's plot, and DFT calculation. Moreover, CM1 showed high sensitivity towards Cd²⁺ with a very low detection limit (19.25 nM). Additionally, the CM1 was recovered and recycled by the addition of EDTA solution that combines with Cd²⁺ ion and, hence, frees up the chemosensor.

Keywords: aqueous medium; chemosensor; curcumin; heavy metals; high sensitivity.