Research on Waste Combustion in the Aspect of Mercury Emissions

Materials (Basel). 2023 Apr 19;16(8):3213. doi: 10.3390/ma16083213.

Abstract

The topic of waste combustion/co-combustion is critical, given the increasingly restrictive legal regulations regarding its environmental aspects. In this paper, the authors present the test results of selected fuels of different compositions: hard coal, coal sludge, coke waste, sewage sludge, paper waste, biomass waste and polymer waste. The authors conducted a proximate and ultimate analysis of the materials and mercury content in them and their ashes. An interesting element of the paper was the chemical analysis of the XRF of the fuels. The authors conducted the preliminary combustion research using a new research bench. The authors provide a comparative analysis of pollutant emissions-especially mercury emission-during the combustion of the material; this is an innovative element of this paper. The authors state that coke waste and sewage sludge are distinguished by their high mercury content. The value of Hg emission during the combustion depends on the initial mercury content in the waste. The results of the combustion tests showed the adequacy of mercury release compared to the emissions of other compounds considered. Small amounts of mercury were found in waste ashes. The addition of a polymer to 10% of coal fuels leads to a reduction in mercury emissions in exhaust gases.

Keywords: combustion; emission; mercury; polymer; waste.

Grants and funding

The paper was carried out under BS/PB-1-100-3011/2023/P (Czestochowa University of Technology, Faculty of Mechanical Engineering and Computer Science). The tests were conducted using the research apparatus of AGH as part of the co-financing of the statutory activity of AGH University of Science and Technology, Faculty of Energy and Fuels (16.16.210.476).