α-Aryl derivatives of carbonyl compounds are important building blocks. Herein, we presented an efficient catalytic system for the α-arylation of aryl ketones with inactive aryl chlorides by firstly using N,N'-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene (IPr)-ligated chiral oxazoline palladacycles, and tolerated a wide range of substrates at low catalyst loadings, leading to the desired products in good to excellent yields.