High-Temperature Syngas Desulfurization and Particulate Filtration by ZnO/Ceramic Filters

T-C Wang; Ling-Wei Wei; H-L Huang; Kuen-Song Lin; H Paul Wang

doi:10.1021/acsomega.2c08260

High-Temperature Syngas Desulfurization and Particulate Filtration by ZnO/Ceramic Filters

ACS Omega. 2023 Apr 6;8(15):13813-13818. doi: 10.1021/acsomega.2c08260. eCollection 2023 Apr 18.

Authors

T-C Wang¹, Ling-Wei Wei¹, H-L Huang², Kuen-Song Lin³, H Paul Wang¹

Affiliations

¹ Department of Environmental Engineering, National Cheng Kung University, Tainan City 70101, Taiwan.
² Department of Safety, Health and Environmental Engineering, National United University, Miaoli 36003, Taiwan.
³ Department of Chemical Engineering and Materials Science, Yuan Ze University, Chung-Li 32003, Taiwan.

Abstract

Combustible gas (e.g., gasification syngas) cleaning at high temperatures can obtain further gains in energy efficiency for power generation and importantly leads to a simplified process and lower cost as a commercially viable source of clean energy. Thus, a feasibility study for high-temperature desulfurization (HTDS) and additional high-temperature particulate filtration (HTPF) of a raw syngas using ZnO sorbent-dispersed Raney CuO (ZnO/R-CuO) and ceramic filter (ZnO/CF) has been carried out. By synchrotron X-ray absorption near-edge structure (XANES) spectroscopy, mainly Zn(II) and Cu(II) are found in the ZnO/R-CuO sorbents. Both ZnO and R-CuO in the sorbents are involved in HTDS (1% H₂S) at 873 K to form ZnS, Cu₂S, and a small amount of CuS and reach relatively high HTDS efficiencies (82-90%). In addition, regeneration of the sulfurized sorbent by oxidation with O₂ at 873 K (HTRG) for 1 h can restore ZnO and CuO for continuous and repetitive HTDS-HTRG cycles. To facilitate the HTDS engineering applications by the ZnO/R-CuO sorbents, their reaction rate constant (8.35 × 10⁴ cm³/g/min) and activation energy (114.8 kJ/mol) at 873 K have also been determined. Furthermore, the ZnO/CF sorbent/filter can perform HTDS and additional HTPF at 873 K with very high particulate removal efficiencies (>98%). This demonstrates the feasibility for hot-syngas cleaning with a much better energy efficiency and lesser cost for cleaner power generation.