PvT Properties and Thermodynamic Property Correlations for the Low Global Warming Potential Hydrofluoroolefin Refrigerant R-1132a (1,1-Difluoroethene)

Int J Thermophys. 2023;44(6):84. doi: 10.1007/s10765-023-03184-4. Epub 2023 Apr 17.

Abstract

R-1132a is increasingly being considered as a low global warming potential component in alternative mixtures to R-23 in specialized low temperature and ultra-low temperature refrigeration systems. Though the thermodynamic properties of R-1132a were investigated in several studies up to 2018, reinvestigations have been carried out in recent years. In order to contribute toward these renewed measurements, the critical parameters of R-1132a were experimentally re-determined. Thirty-two vapor pressures from 240 K to the critical temperature, fifteen saturated vapor and six saturated liquid densities above 254 K and the PvT properties in both the vapor phase (98 points) and liquid phase (34 points) from densities of 50 kg·m-3 to 760 kg·m-3 were also measured. Specific correlations for each of these properties were optimized and compared to previously available data from the literature. Additionally, the Peng-Robinson equation of state was used to represent the aforementioned properties and further utilized to determine the enthalpy and entropy of R-1132a.

Supplementary information: The online version contains supplementary material available at 10.1007/s10765-023-03184-4.

Keywords: Hydrofluoroolefin; Low GWP refrigerant; Low temperature refrigeration; R-1132a; R-23 alternative, Thermodynamic properties; Ultra-low temperature refrigeration.