Light-Driven MXene-Based Microrobots: Mineralization of Bisphenol A to CO2 and H2 O

Small Methods. 2023 Aug;7(8):e2201547. doi: 10.1002/smtd.202201547. Epub 2023 Apr 19.

Abstract

Light-driven magnetic MXene-based microrobots (MXeBOTs) have been developed as an active motile platform for efficiently removing and degrading bisphenol A (BPA). Light-driven MXeBOTs are facilitated with the second control engine, i.e., embedded Fe2 O3 nanoparticles (NPs) for magnetic propulsion. The grafted bismuth NPs act as cocatalysts. The effect of the BPA concentration and the chemical composition of the swimming environment on the stability and reusability of the MXeBOTs are studied. The MAXBOTs, a developed motile water remediation platform, demonstrate the ability to remove/degrade approximately 60% of BPA within just 10 min and achieve near-complete removal/degradation (≈100%) within 1 h. Above 86% of BPA is mineralized within 1 h. The photocatalytic degradation of BPA using Bi/Fe/MXeBOTs demonstrates a significant advantage in the mineralization of BPA to CO2 and H2 O.

Keywords: MXene; bisphenol A; environmental remediation; microrobots; microswimmers; nano/micromotors; photocatalysis.