Near-Room-Temperature Synergetic Response of Magnetism, Dielectricity and Luminescence Based on (C5 NH13 Cl)2 MnBr4

Chemistry. 2023 Jul 6;29(38):e202300598. doi: 10.1002/chem.202300598. Epub 2023 May 22.

Abstract

Multifunctional materials with working temperatures near room temperature are crucial for practical applications. Until now, it is still a great challenge to obtain such materials. In this paper, a complex of (C5 NH13 Cl)2 MnBr4 (1) with a structural phase transition near room temperature is reported. The phase transition induces switchable magnetic properties, dielectric anomalies and luminescent response over the same range of temperatures. It is the first time the synergetic effect of magnetism, dielectricity and luminescence near room temperature have been observed in the same molecular complex.

Keywords: dielectricity; luminescence; magnetism; molecular materials; synergetic response.

MeSH terms

  • Luminescence*
  • Magnetics*
  • Phase Transition
  • Temperature