Catalytic modification of corn straw facilitates the remediation of Cd contaminated water and soil

Abstract

Turning postharvest residue into high-value-added products is crucial for agricultural waste management and environmental remediation. In this proof-of-concept study, nanosized Pt/TiO₂ was used as a model catalyst to modify corn straw (CS) materials through a simple low-temperature oxidation process. This method was demonstrated to be self-sustainable, waste-free, and with high yields. At an optimal temperature of 220 °C, O₂ treatment with 1 wt% Pt/TiO₂ greatly changed ultra-micropore and mesopore structures, dissolved organic carbon, aromatic contents and surface oxygen (O)-containing functional groups in CS products. This treatment resulted in an approximately 5-fold increase of cadmium (Cd) adsorption from aqueous solution and immobilization rate of 43.1% at 7d for bioavailable Cd in soil. Spectroscopic and linear regression analysis demonstrated that both acidic and basic functional groups in CS contributed to Cd adsorption, suggesting chemical adsorption. According to the d-band theory, the unexpected role of catalysts in CS modification could be associated with dissociative adsorption of molecular O₂ on the Pt surface. These results provide insights for the development of economic and sustainable technologies to reutilize agricultural waste biomass for water and soil remediation.

Keywords: Adsorption; Biomass; Cadmium; Modification; Soil remediation; Surface functional group.