Effects of Nitrite/Nitrate-Based Accelerators on Strength and Deformation of Cementitious Repair Materials under Low-Temperature Conditions

Materials (Basel). 2023 Mar 26;16(7):2632. doi: 10.3390/ma16072632.

Abstract

This study aimed to develop a cementitious repair material that can be constructed in cold weather conditions. The addition of nitrite/nitrate-based antifreezing agents has been shown to increase the initial strength of cementitious repair materials in cold weather. However, increasing the amount of these agents may lead to an increase in deformation behavior and shrinkage cracking. In this study, the effects of different types and amounts of nitrite/nitrate-based antifreezing agents on the strength development and deformation behavior of cementitious repair materials under low-temperature conditions were evaluated. As a result, it was found that the addition of a large amount of calcium nitrite can promote hydration and improve the initial strength of the repair material, irrespective of the type of antifreezing agent. However, this also leads to an increase in shrinkage and the concern of shrinkage cracking. Therefore, a repair material that is repairable in winter was developed by balancing the initial strength and deformation behavior through the appropriate selection of antifreezing agents. The developed repair material can be used to repair structures in cold weather conditions, which is of great significance for the construction industry in Hokkaido, Japan.

Keywords: NO2−; NO3−; antifreezing agent; cement-based repair materials; cold weather construction; deformation behavior; strength development.