Metal Oxides Enhance the Absorption Performance of N-Methyldiethanolamine Solution during the Carbon Dioxide Capture Process

Yuming Nie; Ye Li; Huanjun Wang; Dongfang Guo; Lianbo Liu; Yonghong Fu

doi:10.1021/acsomega.2c06482

Metal Oxides Enhance the Absorption Performance of N-Methyldiethanolamine Solution during the Carbon Dioxide Capture Process

ACS Omega. 2023 Mar 21;8(13):11813-11823. doi: 10.1021/acsomega.2c06482. eCollection 2023 Apr 4.

Authors

Yuming Nie^{1

2

3}, Ye Li⁴, Huanjun Wang⁴, Dongfang Guo⁴, Lianbo Liu⁴, Yonghong Fu^{1

2

3}

Affiliations

¹ Xi'an University of Architecture and Technology, Xi'an 710055, China.
² Shaanxi Key Laboratory of Nanomaterials and Nanotechnology, Xi'an 710055, China.
³ Xi'an Clean Energy Key Laboratory, Xi'an 710055, China.
⁴ Huaneng Clean Energy Research Institute, Beijing 100000, China.

Abstract

Fly ash from coal-fired power plants can enter chemical absorbents along with flue gas. Silica and metal oxides are the main components of fly ash. To explore the effect of the metal oxides on absorbents, we analyzed the integrated CO₂ absorption-desorption process using N-methyldiethanolamine (MDEA) as the standard and an amine absorbent after adding different metal oxides. The effects of each metal oxide on CO₂ capture by the MDEA solution, including CO₂ reaction heat, absorption rate, cyclic loading, and carbonation rate, were assessed. It was found that supplementation with appropriate calcium oxide and magnesium oxide proportions accelerates the CO₂ absorption rate and shortens the saturation time of the MDEA solution by 9%-17%. Magnesium oxide and calcium oxide were precipitated as carbonates during absorption. The CO₂ reaction heat of the MDEA solution increased by 95% after adding magnesium oxide, thereby significantly increasing the energy consumption of the desorption process. On the basis of the experimental studies, the increase in CO₂ absorption rate by MDEA after adding MgO and CaO may be mediated through two different mechanisms.