Dealloying Synthesis of Bimetallic (Au-Pd)/CeO2 Catalysts for CO Oxidation

Haiyang Wang; Dongxia Zhang; Ruiyin Zhang; Hao Ma; Huimin Zhang; Ruijuan Yao; Miaomiao Liang; Yuzhen Zhao; Zongcheng Miao

doi:10.1021/acsomega.2c07191

Dealloying Synthesis of Bimetallic (Au-Pd)/CeO₂ Catalysts for CO Oxidation

ACS Omega. 2023 Mar 22;8(13):11889-11896. doi: 10.1021/acsomega.2c07191. eCollection 2023 Apr 4.

Authors

Haiyang Wang¹, Dongxia Zhang¹, Ruiyin Zhang¹, Hao Ma¹, Huimin Zhang¹, Ruijuan Yao¹, Miaomiao Liang¹, Yuzhen Zhao¹, Zongcheng Miao¹

Affiliation

¹ Key Laboratory of Organic Polymer Photoelectric Materials, School of Sciences, Xi'an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, Xijing University, Xi'an, Shaanxi 710123, P. R. China.

Abstract

The nanorod-structured (Au-Pd)/CeO₂ catalysts with different Au/Pd ratios were prepared from Al-Ce-Au-Pd precursor alloys through combined dealloying and calcination treatment. XRD, SEM, TEM, XPS, Raman spectroscopy, and N₂ adsorption-desorption measurements were applied to test the structure and physicochemical properties of samples. Catalytic evaluation results imply that the (Pd_0.15-Au_0.15)/CeO₂ catalyst calcined at 500 °C possesses optimal catalytic activity for CO oxidation when compared with other catalysts with different Au/Pd ratios or (Pd_0.15-Au_0.15)/CeO₂ calcined at other temperatures, whose 50% and 99% reaction temperature can be reached as low as 50 and 85 °C, respectively. This superior catalytic property is attributed to their robust nanorod structure and the introduction of noble bimetal Pd and Au, which can construct a nanoscale interface to access fast electron motion, thus enhancing catalytic efficiency.