Revisiting the melting curve of H2O by Brillouin spectroscopy to 54 GPa

Tomoaki Kimura; Motohiko Murakami

doi:10.1063/5.0137943

Revisiting the melting curve of H₂O by Brillouin spectroscopy to 54 GPa

J Chem Phys. 2023 Apr 7;158(13):134504. doi: 10.1063/5.0137943.

Authors

Tomoaki Kimura¹, Motohiko Murakami¹

Affiliation

¹ Department of Earth Sciences, ETH Zürich, Zürich 8092, Switzerland.

PMID: 37031134
DOI: 10.1063/5.0137943

Abstract

The melting curve of H₂O was investigated up to 54 GPa and ∼2000 K by Brillouin scattering spectroscopy in a diamond anvil cell. A CO₂ laser was used for heating the H₂O sample directly in order to reduce the risk of chemical reactions. The melting was identified based on the appearance of the Brillouin peaks derived from the liquid phase. The longitudinal wave velocity (V_p) of the liquid phase along the melting curve exhibits a smooth increase with pressure. The melting temperature of H₂O shows no kink previously reported but a monotonic increase between 26 and 54 GPa. Present melting data suggest that the melting occurs from body-centered-cubic superionic phase in the pressure-temperature range investigated.