Evaluating fundamental biochar properties in relation to water holding capacity

Sirjana Adhikari; M A Parvez Mahmud; Minh Duc Nguyen; Wendy Timms

doi:10.1016/j.chemosphere.2023.138620

Evaluating fundamental biochar properties in relation to water holding capacity

Chemosphere. 2023 Jul:328:138620. doi: 10.1016/j.chemosphere.2023.138620. Epub 2023 Apr 4.

Authors

Sirjana Adhikari¹, M A Parvez Mahmud², Minh Duc Nguyen³, Wendy Timms⁴

Affiliations

¹ School of Engineering, Deakin University, Geelong, Victoria, 3216, Australia; Centre for Sustainable Bioproducts, Deakin University, Geelong, Victoria, 3216, Australia. Electronic address: adhikaris@deakin.edu.au.
² School of Electrical, Mechanical and Infrastructure Engineering, University of Melbourne, Parkville, Victoria, 3010, Australia. Electronic address: parvez.mahmud@unimelb.edu.au.
³ School of Engineering, Deakin University, Geelong, Victoria, 3216, Australia. Electronic address: minhd@deakin.edu.au.
⁴ School of Engineering, Deakin University, Geelong, Victoria, 3216, Australia; Centre for Sustainable Bioproducts, Deakin University, Geelong, Victoria, 3216, Australia. Electronic address: wendy.timms@deakin.edu.au.

PMID: 37023908
DOI: 10.1016/j.chemosphere.2023.138620

Abstract

Biochar products that hold and release water within a stable carbonised porous structure provide many opportunities for climate mitigation and a range of applications such as for soil amendments. Biochar that are produced from various organic feedstocks by pyrolysis can provide multiple co-benefits to soil including improving soil health and productivity, pH buffering, contaminant control, nutrient storage, and release, however, there are also risks for biochar application in soils. This study evaluated fundamental biochar properties that influence Water Holding Capacity (WHC) of biochar products and provides recommendations for testing and optimising biochar products prior to soil applications. A total of 21 biochar samples (locally sourced, commercially available, and standard biochars) were characterised for particle properties, salinity, pH and ash content, porosity, and surface area (with N₂ as adsorbate), surface SEM imaging, and several water testing methods. Biochar products with mixed particle size, irregular shapes, and hydrophilic properties were able to rapidly store relatively large volumes of water (up to 400% wt.). In contrast, relatively less water (as low as 78% wt.) was taken up by small-sized biochar products with smooth surfaces, along with hydrophobic biochars that were identified by the water drop penetration test (rather than contact angle test). Water was stored mostly in interpore spaces (between biochar particles) although intra-pore spaces (meso-pore and micropore scale) were also significant for some biochars. The type of organic feedstock did not appear to directly affect water holding, although further work is needed to evaluate mesopore scale processes and pyrolytic conditions that could influence the biochemical and hydrological behaviour of biochar. Biochars with high salinity, and carbon structures that are not alkaline pose potential risks when used as soil amendments.

Keywords: Carbon; Hydrophilic; Hydrophobic; Pyrolysis; pyCCS.

MeSH terms

Carbon
Charcoal* / chemistry
Soil / chemistry
Water*

Substances

biochar
Water
Charcoal
Carbon
Soil