High-precision accelerometers play an important role in satellite gravity field missions to measure the non-conservative forces acting on the satellites. To map the Earth's gravity field, the accelerometer data must be time-tagged using the on-board global navigation satellite system time reference. For example, in the Gravity Recovery and Climate Experiment mission, the time-tag error of the accelerometers must be within 0.1 ms with respect to the satellite clock. To realize this requirement, the time delay between the actual measurement time and the nominal time of the accelerometer should be considered and corrected. This paper presents the techniques for measuring the absolute time delay of an electrostatic accelerometer on the ground, where this delay is mainly introduced by the low-noise scientific data read-out system, which is based on a Σ-Δ (sigma-delta) analog-to-digital converter (ADC). First, the time-delay sources of the system are theoretically analyzed. Then, a time-delay measurement method is proposed, and its principle and system error are presented. Finally, a prototype is built to demonstrate and investigate the feasibility of the method. Experimental results show that the absolute time delay of the read-out system is 150.80 ± 0.04 ms. This important value is the basis for the final time-tag error correction of the scientific accelerometer data. Meanwhile, the time-delay measurement method described in this paper is also useful for other data acquisition systems.