Targeting of platinum capture under 1+1 aqua regia using robust and recyclable polymeric polyamine resin: Adsorption performance and mechanism

Abstract

The targeted capture of platinum from complex and harsh acidic digests such as those platinum-containing secondary resources is essential from the perspectives of green development. Here, a polyamine chelating resin (CMPs-PEI) with excellent selectivity and acid resistance was prepared by a nucleophilic substitution reaction using chloromethylated polystyrene as the parent and polyethyleneimine as the modifier. The experimental results revealed that the adsorbent showed excellent adsorption effect on platinum under different acidities, and its maximum adsorption capacity was up to 337 mg/g at pH 2. More impressively, a rather high capacity of 162.41 mg/g was achieved in 1 + 1 aqua regia (pH -0.7), which was much higher than other adsorbent materials under the same conditions. In addition, the recovery of platinum by CMPs-PEI in practical platinum-containing iron concentrate abatement solution was 100 %. Mechanistic studies showed that the protonated amine groups on CMPs-PEI bound PtCl₆^2- and partially reduced PtCl₄^2- by electrostatic attraction. Meanwhile, the excellent regeneration performance of CMPs-PEI indicated that it showed great potential for green and economic recovery of precious metal ions.

Keywords: Adsorption; Aqua regia; Chelating resin; Platinum.