Nanocomposite conductive fibers are of great significance in applications of wearable devices, smart textiles, and flexible electronics. Integration of conductive nanomaterials into flexible bio-based fibers with multifunctionality remains challenging due to interface failure, poor flexibility, and inflammability. Although having broader applications in textiles, regenerated cellulose fibers (RCFs) cannot meet the requirements of wearable electronics owing to their intrinsic insulation. In this study, we constructed conductive RCFs fabricated by coordinating copper ions with cellulose and reducing them into stable Cu nanoparticles coated on their surface. The Cu sheath offered excellent electrical conductivity (4.6 × 105 S m-1), electromagnetic interference shielding, and enhanced flame retardance. Inspired by plant tendrils, the conductive RCF was wrapped around an elastic rod to develop wearable sensors for human health and motion monitoring. The resultant fibers not only form stable conductive nanocomposites on the fiber surface by chemical bonds but also exhibit a huge potential for wearable devices, smart sensors, and flame-retardant circuits.
Keywords: copper sheath; copper-coordinated cellulose; electrical conductivity; electromagnetic interference shielding; flame retardance; flexible sensor.