A Numerical Thermo-Chemo-Flow Analysis of Thermoset Resin Impregnation in LCM Processes

Polymers (Basel). 2023 Mar 22;15(6):1572. doi: 10.3390/polym15061572.

Abstract

This paper presents a numerical framework for modelling and simulating convection-diffusion-reaction flows in liquid composite moulding (LCM). The model is developed in ANSYS Fluent with customised user-defined-functions (UDFs), user-defined-scalar (UDS), and user-defined memory (UDM) codes to incorporate the cure kinetics and rheological characteristics of thermoset resin impregnation. The simulations were performed adopting volume-of-fluid (VOF)-a multiphase flow solution-based on finite volume method (FVM). The developed numerical approach solves Darcy's law, heat transfer, and chemical reactions in LCM process simultaneously. Thereby, the solution scheme shows its ability to provide information on flow-front, viscosity development, degree of cure, and rate of reaction at once unlike existing literature that commonly focuses on impregnation stage and cure stage in isolation. Furthermore, it allows online monitoring, controlled boundary conditions, and injection techniques (for design of manufacturing) during the mould filling and curing stages. To examine the validity of the model, a comparative analysis was carried out for a simple geometry, in that the numerical results indicate good agreement-3.4% difference in the degree of cure compared with previous research findings.

Keywords: CFD; cure kinetics; curing stage; filling stage; liquid composite moulding; rheology.

Grants and funding

This research received no external funding. For the purpose of open access, the author applied a Creative Commons Attribution (CC BY) licence to any Author Accepted Manuscript version arising from this submission.