Extrusion-free-form printing of alumina ceramics has the advantages of low cost, short cycle time, and high customization. However, some problems exist, such as the low solid content of ceramic paste and the unsatisfactory mechanical properties of pure alumina ceramics. In this study, SiC nanoparticles were used as a reinforcement phase added to the alumina ceramic matrix. Methylcellulose is used as the binder in the raw material system. Ammonium polyacrylate is used as a dispersant to change the rheological properties of the slurry and increase the solid content of ceramics. SiC nanoparticle-strengthened alumina ceramics were successfully prepared by the extrusion process. The relative settling height and viscosity of ceramic slurries were characterized. The sintering shrinkage of composite ceramics was tested. The flexural strength, fracture toughness, and hardness of the ceramics were characterized. The strengthening and toughening mechanisms of the composite ceramics were further explained by microscopic morphology analysis. Experimental results show that when the content of the dispersant is 1 wt.%, the rheological properties of the slurry are the best. Maximum measured bending strength (227 MPa) and fracture toughness (5.35 MPa·m1/2) were reached by adding 8 wt% SiC nanoparticles; compared with pure alumina ceramics, flexural strength and fracture toughness increased by 42% and 41%, respectively. This study provides a low-cost and effective method for preparing ceramic composite parts.
Keywords: 3D printing; SiC nanoparticles; alumina; mechanical properties.