Nanocomposites as Substituent of Cement: Structure and Mechanical Properties

Materials (Basel). 2023 Mar 16;16(6):2398. doi: 10.3390/ma16062398.

Abstract

To date, the scientific research in the field of recycling of construction and demolition wastes was focused on the production of concrete, cements, and bricks. The attainment of these products was limited to the addition of suitable binder contents, such as lime or cement, compaction, and possibly heat treatment, without a concrete recycling method. In this paper, new cement materials consisting of 2.5 weight% composite and originating from construction and demolition waste powder, were prepared and investigated in view of applications in the construction industry as a substituent of cement. The materials with recycled powder from construction and demolition wastes were characterized by X-ray diffraction (XRD), infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy. The XRD data indicate vitroceramic structures with varied crystalline phases. The NMR relaxometry data show four reservoirs of water associated with bounded water and with three types of pores in the composite construction material. The micro-Vickers hardness was measured to reflect the influence of composite nature in the local mechanical properties of the composite-cement for the mixture with Portland cement and (EC) expired cement.

Keywords: IR; NMR; Vickers hardness; XRD; composite-cement.

Grants and funding

The APC was funded by Technical University of Cluj-Napoca 57/2021.