Spectroscopic Study of Five-Coordinated Thermal Treated Alumina Formation: FTIR and NMR Applying

Int J Mol Sci. 2023 Mar 8;24(6):5151. doi: 10.3390/ijms24065151.

Abstract

This work represents research into materials designed to improve the environment. The study was carried out on aluminum hydroxide xerogels and alumina catalysts obtained by the Controlled Double Jet Precipitation (CDJP) process at different pH values. It has been shown that the pH of the CDJP process determines the content of aluminum-bound nitrate ions in the aluminum hydroxide. These ions are removed at a higher temperature than the decomposition of ammonium nitrate. The high content of aluminum-bound nitrate ions determines the structural disorder of the alumina and the high content of the penta-coordinated alumina catalyst.

Keywords: aluminum oxide; controlled double jet precipitation; nuclear magnetic resonance spectroscopy; penta-coordinated structure.

MeSH terms

  • Aluminum / chemistry
  • Aluminum Hydroxide / chemistry
  • Aluminum Oxide* / chemistry
  • Nitrates*
  • Spectroscopy, Fourier Transform Infrared

Substances

  • Aluminum Oxide
  • aluminum nitrate
  • Nitrates
  • Aluminum Hydroxide
  • Aluminum

Grants and funding

This research received no external funding.