Trends in removal of pharmaceuticals in contaminated water using waste coffee and tea-based materials with their derivatives

Abstract

The introduction of large amounts of pharmaceuticals into the environmental waters is well-documented in literature with their occurrence reported in all different water matrices accessible to humans and animals. At the same time, the increasing consumption of coffee and tea-based beverages results in the generation of solid waste, which is mostly disposed-off in the environment. To minimize environmental pollution, coffee and tea-based materials have been proposed as suitable options to remove pharmaceuticals in environmental waters. Therefore, this article provides a critical review on the preparation and applications of coffee and tea-based materials in removing pharmaceuticals from contaminated water. In this context, most studies in literature focused on the applications of these materials as adsorbents, while only limited work on their role in degradation of pharmaceuticals is discussed. The successful application in adsorption studies is attributed to high surface areas of adsorbents and the ability to easily modify the adsorbent surfaces by incorporating functional groups that provide additional oxygen atoms, which promote easy interactions with pharmaceuticals. Hence, the adsorption mechanisms are mostly described by hydrogen bonding, electrostatic and π-π interactions with sample pH playing a dominant role in the adsorption process. Overall, the present article focused on the developments, trends and future research direction on the preparations and applications of coffee and tea-based materials for efficient removal of pharmaceuticals in water. PRACTITIONER POINTS: Review of tea and coffee wastes application for removal of pharmaceuticals in water Key applications in adsorption and degradation of pharmaceuticals in water Removal mostly explained by hydrogen bonding, electrostatic, and π-π interactions Trends, gaps, and future research to be explored are reviewed and highlighted.

Keywords: adsorption; degradation; pharmaceuticals; waste materials.