Plant-assisted synthesis and characterization of MnO2 nanoparticles for removal of crystal violet dye: an environmental remedial approach

Abstract

The current study is focused on the use of the Caryota mitis Lour. (Fishtail palm) flower extract as a reducing agent for the preparation of manganese dioxide (MnO₂) nanoparticles. Scanning electron microscopy (SEM), four-phase infrared analysis (FT-IR), and x-ray diffraction (XRD) methods were used to characterize the MnO₂ nanoparticles. The nature of MnO₂ nanoparticles was revealed by an absorption peak at 590 nm in a spectrophotometer (A1000). Then, these MnO₂ nanoparticles were applied to decolorize the crystal violet dye. At 0.004% dye concentration, pH 4, and concentration of MnO₂ nanoparticles of 0.005 g/L at temperatures of 50 °C, the target dye was decolorized by 91.3%. Percent reductions in COD and TOC were found to be 92.1% and 90.6%, respectively. Finally, the dye decolorization pathway was proposed based on the experimental findings.

Keywords: Caryota mitis; Crystal violet dye; Decolorization; FE-SEM; FTIR; TOC and COD; XRD.